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期刊

標題

Switchgrass Biochar Affects Two Aridisols

作者

J. A. Ippolito, J. M. Novak, W. J. Busscher, M. Ahmedna, D. Rehrah, D. W. Watts

名稱(期刊/節目)

Journal of Environmental Quality

期刊期數/節目集數

Volume 41, Issue 4, Pages 1123-1130

出版單位

Wiley

出版年月日

2012/7/1

原文摘要

The use of biochar has received growing attention because of its ability to improve the physicochemical properties of highly weathered Ultisols and Oxisols, yet very little research has focused on its effects in Aridisols. We investigated the effect of low or high temperature (250 or 500°C) pyrolyzed switchgrass (Panicum virgatum L.) biochar on two Aridisols. In a pot study, biochar was added at 2% w/w to a Declo loam (Xeric Haplocalcids) or to a Warden very fine sandy loam (Xeric Haplocambids) and incubated at 15% moisture content (by weight) for 127 d; a control (no biochar) was also included. Soils were leached with 1.2 to 1.3 pore volumes of deionized H2O on Days 34, 62, 92, and 127, and cumulative leachate Ca, K, Mg, Na, P, Cu, Fe, Mn, Ni, Zn, NO3–N, NO2–N, and NH4–N concentrations were quantified. On termination of the incubation, soils were destructively sampled for extractable Cr, Cu, Fe, K, Mg, Mn, Na, Ni, P, Zn, NO3–N, and NH4–N, total C, inorganic C, organic C, and pH. Compared with 250°C, the 500°C pyrolysis temperature resulted in greater biochar surface area, elevated pH, higher ash content, and minimal total surface charge. For both soils, leachate Ca and Mg decreased with the 250°C switchgrass biochar, likely due to binding by biochar's functional group sites. Both biochars caused an increase in leachate K, whereas the 500°C biochar increased leachate P. Both biochars reduced leachate NO3–N concentrations compared with the control; however, the 250°C biochar reduced NO3–N concentrations to the greatest extent. Easily degradable C, associated with the 250°C biochar's structural make‐up, likely stimulated microbial growth, which caused NO3–N immobilization. Soil‐extractable K, P, and NO3–N followed a pattern similar to the leachate observations. Total soil C content increases were linked to an increase in organic C from the biochars. Cumulative results suggest that the use of switchgrass biochar prepared at 250°C could improve environmental quality in calcareous soil systems by reducing nutrient leaching potential.

原文摘要簡述

因生物炭的使用能夠改善高度風化的極育土和氧化土的理化特性而受到越來越多的關注,但是很少有研究集中在其對旱境土的影響上。我們研究了低溫或高溫(250或500°C)熱解柳枝稷(Panicum virgatum L.)生物炭對兩種旱境土的影響。在一項盆栽試驗中,將生物炭以2% w/w的量添加到德克洛(Declo)壤土(Xeric Haplocalcids)或沃爾登(Warden)極細的沙壤土(Xeric Haplocambids)中,並在水分含量15% (按重量計)下培養127天;其中也包括一對照(無生物炭)。在第34、62、92和127天,分別用1.2至1.3孔隙容量的去離子水淋洗土壤,並量化了累積Ca、K、Mg、Na、P、Cu、Fe、Mn、Ni、Zn、NO3–N、NO2–N及NH4–N淋溶液的濃度。培養結束後,對土壤進行了破壞性採樣,包括可萃取的Cr、Cu、Fe、K、Mg、Mn、Na、Ni、P、Zn、NO3-N和NH4-N、總碳、無機碳、有機碳以及pH值。與250°C相比,500°C的熱解溫度導致更大的生物炭表面積、更高的pH值、更多的灰分含量和最小的總表面電荷。對於兩種土壤,淋溶液中鈣和鎂的含量隨250°C柳枝稷生物炭而降低,很可能是由於生物炭的官能基位點結合所致。兩種生物炭均導致淋溶液鉀的增加,而500°C生物炭則提高了淋溶液磷的濃度。與對照組相比,兩種生物炭均降低了淋溶液中NO3-N的濃度;然而,250°C生物炭以最大程度降低了NO3-N濃度。容易降解的碳與250°C的生物炭的結構組成有關,很可能刺激了微生物的生長,從而導致NO3-N的固定化。土壤可提取的鉀、磷和NO3-N遵循與淋溶液觀察相似的模式。土壤總碳含量的增加與生物炭中有機碳的增加有關。累積結果顯示,使用250°C製備的柳枝稷生物炭可以通過減少養分淋失的潛力來改善石灰性土壤系統的環境品質。

關鍵字

switchgrass biochar, Aridisols, Xeric Haplocalcids, Xeric Haplocambids, pyrolysis, leachate

連結

https://doi.org/10.2134/jeq2011.0100

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